four (m, 4H, CH2), 1.98.86 (m, 22H, CH2), 1.80.73 (m, 4H, CH2), 1.70.65 (m, 4H

4 (m, 4H, CH2), 1.98.86 (m, 22H, CH2), 1.80.73 (m, 4H, CH2), 1.70.65 (m, 4H, CH 2 ), 1.59.37 (m, 44H, CH two ), 1.36.30 (m, 8H, CH two ),Beilstein J. Org. Chem. 2013, 9, 2852861.1.28.16 (m, 8H, CH2), 1.01.94 (m, 27H, CH3), 0.93.90 (m, 6H, CH3), 0.83.78 (m, 9H, CH3), 0.75 (t, J = 7.3 Hz, 3H, CH three ); 13 C NMR (CDCl 3 , one hundred MHz) 149.0, 148.9, 148.eight, 137.six, 136.1, 135.four, 129.two, 128.1, 127.two, 124.0, 123.three, 108.7, 107.two, 107.0, 106.9, 106.6, 106.five, 105.9, 71.6, 70.5, 70.2, 69.7, 69.6, 69.five, 69.four, 69.1, 69.0, 29.2, 29.1, 29.0, 28.4, 28.three, 22.six, 14.1; anal. calcd for C138H192O18: C, 77.49; H, 9.05; found: C, 77.77; H, 9.09.14. Hassheider, T.; Benning, S. A.; Kitzerow, H.-S.; Achard, M.-F.; Bock, H. Angew. Chem., Int. Ed. 2001, 40, 2060063. doi:10.1002/1521-3773(20010601)40:112060::AID-ANIE20603.three.CO ;2-8 15. Freudenmann, R.; Behnisch, B.; Hanack, M. J. Mater. Chem. 2001, 11, 1618624. doi:ten.1039/b100083g 16. Diring, S.; Camerel, F.; Donnio, B.; Dintzer, T.; Toffanin, S.; Capelli, R.; Muccini, M.; Ziessel, R. J. Am. Chem. Soc. 2009, 131, 181778185. doi:10.1021/ja908061q 17. Mei, J.; Diao, Y.; Appleton, A. L.; Fang, L.; Bao, Z. J. Am. Chem. Soc. 2013, 135, 6724746. doi:ten.1021/ja400881n 18. Schmidt-Mende, L.; Fechtenk ter, A.; M len, K.; Moons, E.; Friend, R. H.; MacKenzie, J. D. Science 2001, 293, 1119122. doi:10.1126/science.293.5532.1119 19. Hayashi, H.; Nihashi, W.; Umeyama, T.; Matano, Y.; Seki, S.; Shimizu, Y.; Imahori, H. J. Am. Chem. Soc. 2011, 133, 107360739. doi:10.1021/ja203822q 20. Geerts, Y. H.; Debever, O.; Amoto, C.; Sergeyev, S. Beilstein J. Org. Chem. 2009, 5, No. 49. doi:ten.3762/bjoc.five.49 21. Kumar, S. Liq. Cryst. 2005, 32, 1089113. doi:10.1080/02678290500117415 22. Imrie, C. T.; Henderson, P. A. Chem. Soc. Rev. 2007, 36, 2096124.Iniparib doi:10.1039/b714102e 23. Imrie, C. T.; Henderson, P. A.; Yeap, G.-Y. Liq. Cryst. 2009, 36, 75577. doi:10.1080/02678290903157455 24. M ler, M.; Tsukruk, V.; Wendorff, J. H.; Bengs, H.; Ringsdorf, H. Liq. Cryst. 1992, 12, 176. doi:ten.1080/02678299208029035 25. Maliszewskyj, N. C.; Heiney, P. A.; Josefowicz, J. Y.; Plesnivy, T.; Ringsdorf, H.; Schuhmacher, P. Langmuir 1995, 11, 1666674. doi:10.1021/la00005a040 26. Tsukruk, V. V.; Bengs, H.; Ringsdorf, H. Langmuir 1996, 12, 75457. doi:10.1021/la9506133 27. Kumar, S.; Schuhmacher, P.; Hendersen, P.; Rego, J.; Ringsdorf, H. Mol. Cryst. Liq. Cryst. 1996, 228, 21122. doi:10.1080/10587259608034598 28. Mahlstedt, S.; Janietz, D.; Stracke, A.; Wendorff, J. H. Chem. Commun. 2000, 156. doi:10.1039/a907770g 29. Kaller, M.; Staffeld, P.; Haug, R.; Frey, W.Mirabegron ; Giesselmann, F.PMID:23927631 ; Laschat, S. Liq. Cryst. 2011, 38, 53153. doi:10.1080/02678292.2011.558215 30. Kaller, M.; Beardsworth, S. J.; Staffeld, P.; Tussetschl er, S.; Gie lmann, F.; Laschat, S. Liq. Cryst. 2012, 39, 60718. doi:10.1080/02678292.2012.668720 31. Gupta, S. K.; Raghunathan, V. A.; Lakshminarayanan, V.; Kumar, S. J. Phys. Chem. B 2009, 113, 128872895. doi:ten.1021/jp9042254 32. Kong, X.; He, Z.; Zhang, Y.; Mu, L.; Liang, C.; Chen, B.; Jing, X.; Cammidge, A. N. Org. Lett. 2011, 13, 76467. doi:10.1021/ol103018v 33. Zelcer, A.; Donnio, B.; Bourgogne, C.; Cukiernik, F. D.; Guillon, D. Chem. Mater. 2007, 19, 1992006. doi:ten.1021/cm062949b 34. Miao, J.; Zhu, L. Chem. Mater. 2010, 22, 19706. doi:ten.1021/cm902731u 35. Miao, J.; Zhu, L. J. Phys. Chem. B 2010, 114, 1879887. doi:ten.1021/jp910053e 36. Boden, N.; Bushby, R. J.; Cammidge, A. N.; El-Mansoury, A.; Martin, P. S.; Lu, Z. B. J. Mater. Chem. 1999, 9, 1391402. doi:10.